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A repeat performance was not meant to be, as Clijsters was wide on match point to end any chance at becoming the eighth woman to repeat as Aussie champion.
Azarenka is 3-3 in her career against Sharapova, with two of those wins coming in finals.
The winner of Saturday's title match will become the new world No. 1, supplanting Clijsters' quarterfinal victim, Caroline Wozniacki. Sharapova has not held the top ranking since the week of June 8, 2007.
The 21-year-old Kvitova missed wildly on an overhead smash to lose her second service game, the first of three breaks for Sharapova in the opening set.
Sharapova, seeded fourth, lost the second set, and was down 0-30 at 4-4 in the third before a replay reversal gave her new life. The Russian won the next four points to put the pressure back on Kvitova, who could not hold serve thanks to several unforced errors in the final game.
The former world No. 1 Sharapova's last major title came at the 2008 Aussie Open. The Russian was the Aussie runner-up in 2007.
In doing so, Azarenka ended another memorable performance Down Under by Clijsters, who has stated she will retire after the Summer Olympics in London.
Clijsters, the 11th seed, quickly evened the match before falling behind 4-1 in the third. She held serve and trailed 40-0 in the next game before earning another break to get back on serve.
But Azarenka, riding a 10-match winning streak after winning in Sydney earlier this month, earned her fourth break of the match to serve for a spot in the final.
In the quarterfinals, Clijsters fought off four match points against last year's Aussie runner-up to her, Li Na.
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Michael Vick is back, Brett Favre isn't and the NFC East remains the best division in the NFC, maybe in all of football.
As players start to gather for the start of another season, some things change and some stay the same in the world of the NFL.
The NFC East has been the dominant division in the National Conference for a while, despite limited playoff success, save for the New York Giants surprise Super Bowl win two seasons ago.
Hell, there's a generation of kids in Texas who have never seen the Cowboys win a playoff game (last win was in 1996).
But collectively, the Giants, Eagles, Cowboys and Redskins (well, maybe not so much the Redskins) are as good as a division gets in an NFC conference that has struggled to stay competitive with the AFC side.
Sports bettors have both acknowledged the NFC East's dominance, as one glance at the NFL future odds menu will show.
Looking over the NFL betting odds at online sports book MySportsbook.com we see the top three teams listed to win the NFC Championship are all from the NFC East:
Dallas Cowboys - 7 - 1
Philadelphia Eagles - 13 - 2
New York Giants - 9 - 2
Slotting in behind these three are two teams from the NFC North: the Minnesota Vikings (15-2) and the Chicago Bears (10-1).
Again, despite the lack of recent playoff success, the Dallas Cowboys are popular with the sports betting community, as they hold 14% of all the money wagered on who will win the NFC Championship.
So far, the New York Giants are the bettors' favorite to represent their conference in the Super Bowl, as they have 24% of the overall NFC Championship betting volume.
And what about the Philadelphia Eagles? For the most part, the Eagles had a very productive offseason, the kind that could bring them back to the top.
They had a good draft adding the likes of WR Jeremy Maclin and RB LeSean McCoy.
Unfortunately, the team received a blow when long-time defensive coordinator Jim Johnson passed away on Tuesday.
But this team will make a real run at the division title this year. Going into the regular season, Philly is listed at +240 to win the division.
Last season the Eagles were 9-6-1 SU and 10-6 ATS.
Teams from the NFC East will play teams from the AFC West in the regular season and the Eagles haven't really been a good bet in the last 20 games against the likes of San Diego, Oakland, K.C. and Denver, only going 8-12 ATS.
Two seasons removed from that Super Bowl title, the New York Giants see themselves listed as the odds-on favorite in NFC East championship futures at +162.
Plaxico Burress is gone and with him all the bad publicity surrounding the gun in the sweatpants incident, but can they replace him in the offense?
Last season the Giants were a very reliable bet going 12-4 ATS.
In the Giants' last 20 games against fellow teams from the NFC East; they are 13-7 ATS.
Dallas is listed at +240 to win the division.
Dallas went 9-7 SU and 7-9 ATS last season and with the amount of talent the Cowboys have, a similar performance won't do.
The Cowboys have been atrocious against divisional rivals, going 6-14 ATS in their last 20.
The Washington Redskins are longshots to win the division at +550.
Visit MySportsbook.com for free sportsbook odds RSS feeds go to MySportsbook.com for all your betting football needs.
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